THE UNSYMMETRICAL SILAKETAL AS A NEUTRAL, REMOVABLE TETHER FOR EFFECTING INTRAMOLECULAR DIELS-ALDER REACTIONS

被引：47

作者：

GILLARD, JW ^{[1
]}

FORTIN, R ^{[1
]}

GRIMM, EL ^{[1
]}

MAILLARD, M ^{[1
]}

TJEPKEMA, M ^{[1
]}

BERNSTEIN, MA ^{[1
]}

GLASER, R ^{[1
]}

机构：

[1] MERCK FROSST CTR THERAPEUT RES,POB 1005,POINTE CLAIRE,QUEBEC,CANADA

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)92029-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Silaketals, in which reactive dienes and dienophiles are linked, can participate in intramolecular Diels-Alder reactions to produce products with a high degree of stereocontrol and with regiochemistry opposite to that predicted by bond polarization models.

引用

页码：1145 / 1148

页数：4

共 18 条

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