SYNTHESIS OF MACROCYCLIC HOMOPROPARGYLIC ALCOHOLS THROUGH INTRAMOLECULAR SE' ADDITION OF ALLENYLSTANNANES AND THEIR SUBSEQUENT CONVERSION TO 2,5-FURANOCYCLES

被引：38

作者：

MARSHALL, JA

WANG, XJ

机构：

[1] Department of Chemistry and Biochemistry, University of South Carolina, Columbia

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 22期

关键词：

D O I：

10.1021/jo00022a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 2,5-furanocyclododecenes 16, 20, and 24 have been prepared by a new route involving intramolecular S(E)' addition of propargylic stannanes 3, 6, and 9 then exposure of the derived allenones 14, 19, and 23 to AgN-O3-CaCO3 in aqueous acetone at room temperature.

引用

收藏

页码：6264 / 6266

页数：3

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