ORGANORHODIUM COMPLEX ON SMECTITE CLAY - PREPARATION, CHARACTERIZATION, AND CATALYTIC ACTIVITY FOR THE HYDROFORMYLATION OF VINYLSILANES

被引：28

作者：

VALLI, VLK

ALPER, H

机构：

[1] Department of Chemistry, University of Ottawa, Ottawa, Ontario, KIN 6N5

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 02期

关键词：

D O I：

10.1021/cm00050a019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sodium montmorillonite reacts with the dimer of chloro(1,5-cyclooctadiene)rhodium(I) in dichloromethane to form a material (Rh-clay) in which rhodium is covalently attached to the silicate sheets of montmorillonite. Linear silylaldehydes were obtained, as the major or only product, in excellent yield by the hydroformylation of trialkylvinylsilanes or triphenylvinylsilane catalyzed by Rh-clay.

引用

页码：359 / 362

页数：4

共 39 条

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