PALLADIUM-CATALYZED DECOMPOSITION OF AQUEOUS ALKALI-METAL FORMATE SOLUTIONS

被引：76

作者：

WIENER, H ^{[1
]}

SASSON, Y ^{[1
]}

BLUM, J ^{[1
]}

机构：

[1] HEBREW UNIV JERUSALEM,DEPT ORGAN CHEM,JERUSALEM,ISRAEL

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1986年 / 35卷 / 03期

关键词：

CARBON - CATALYSTS - Palladium - HYDROGEN - POTASSIUM COMPOUNDS - Decomposition;

D O I：

10.1016/0304-5102(86)87075-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Aqueous sodium and potassium formate solutions under catalytic decomposition, under mild conditions, into molecular hydrogen and hydrogen carbonate in the presence of palladium on carbon. Both the formate and water hydrogen atoms are involved in the process and undergo fast exchange. Some kinetic and mechanistic features of the decomposition reaction are reported.

引用

页码：277 / 284

页数：8

共 27 条

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