EFFECT OF CRYSTALLITE SIZE ON THE CHEMICAL-COMPOSITIONS OF THE STAGE-1 ALKALI METAL-GRAPHITE INTERCALATION COMPOUNDS

被引：53

作者：

FUJIMOTO, H ^{[1
]}

MABUCHI, A ^{[1
]}

TOKUMITSU, K ^{[1
]}

KASUH, T ^{[1
]}

AKUZAWA, N ^{[1
]}

机构：

[1] TOKYO NATL COLL TECHNOL,DEPT IND CHEM,HACHIOJI,TOKYO 193,JAPAN

来源：

CARBON | 1994年 / 32卷 / 02期

关键词：

CHEMICAL COMPOSITION; RAPHITE; ALKALI METAL; LI SECONDARY BATTERY;

D O I：

10.1016/0008-6223(94)90182-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The relation between the compositions of alkali metal-graphite intercalation compounds and the crystallite size of pristine graphite was mathematically analyzed taking into account the in-plane structure and the stacking sequence of the graphite intercalation compounds. It has been found that the atomic ratio of carbon and alkali metal in GICs, C/M (M = Li, K. Rb, and Cs) was approximated by a function of the crystallite size (L(a) and L(c)) and the interlayer spacing (d002) of the pristine graphite. The derived equation shows good agreement with the experimental results previously reported.

引用

页码：193 / 198

页数：6

共 9 条

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