MOLECULAR-STRUCTURE OF ANSA-COMPOUND (ETA(5)-C5H4)CME(2)(ETA(5)-C9H6)TICL2

被引：2

作者：

MKOYAN, SG

ALIEV, ZG

ATOVMYAN, LO

IVCHENKO, PV

机构：

[1] MOSCOW MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 000958,RUSSIA

[2] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1995年 / 44卷 / 02期

关键词：

STRUCTURE; ANSA-COMPLEXES; TITANOCENES;

D O I：

10.1007/BF00702139

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of a new ansa compound, (eta(5)-C5H4)CMe(2)(eta(5)-C9H6)TiCl2 (1), was studied by X-ray analysis: a = 15.00(1), b = 15.500(5), c = 13.032(4) Angstrom, beta = 92.66 degrees(4), V = 3025.1(1) Angstrom(3), space group P21/alpha, R = 0.038. The distorted tetrahedral coordination sphere of the Ti atom is formed by two Cl atoms and two pi-ligands. It was proposed that the angle (tau) between the C-M direction and the line normal to M-Cp can be considered as one of the geometric parameters characteristic of the ''structure-properties'' correlation.*

引用

页码：296 / 299

页数：4

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[2]

ANTBERG M, 1989, PROPYLENE POLYM STER

[3]

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[4]

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