NEW SYNTHETIC TRICKS - TRIMETHYLSILYL TRIFLATE MEDIATED CLEAVAGE OF HINDERED SILYL ETHERS

被引：41

作者：

BOU, V

VILARRASA, J

机构：

[1] Department de Química Orgànica, Facultat de Química, Universitat de Barcelona(III), 08028 Barcelona, Catalonia

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 04期

关键词：

D O I：

10.1016/0040-4039(90)87036-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An alternative, mild procedure for the cleavage of t-butyldimethyisilyl and triphenyisilyl ethers to alcohols is shown, which is based on an exchange reaction with trimethylsilyl triflate below 0 °C. t-Butyldiphenylsilyl groups are not removed under these conditions. © 1990.

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页码：567 / 568

页数：2

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