ANODIC-OXIDATION OF LEAD IN SULFURIC-ACID-SOLUTIONS - THE EFFECT OF DIFFERENT PERCHLORATE SALTS ON PLANTE FORMATION

被引：5

作者：

AHLBERG, E ^{[1
]}

BERGHULT, B ^{[1
]}

机构：

[1] GOTHENBURG UNIV,S-41296 GOTHENBURG,SWEDEN

来源：

JOURNAL OF POWER SOURCES | 1990年 / 32卷 / 03期

关键词：

Electrolytes - Salts - Solutions - Sulfuric Acid;

D O I：

10.1016/0378-7753(90)87017-L

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of lead to PbO2 in dilute sulphuric acid has been studied. Small amounts of perchlorate ions in the electrolyte increase the oxidation rate and probably influence the ratio between α- and β-PbO2. The cation of the perchlorate salt is important for the discharge properties of the PbO2 formed. The discharge capacity, the active surface area and the self discharge current all increase in the sequence K+ < Na+ < Li+ < H+. © 1990.

引用

页码：243 / 251

页数：9

共 19 条

[1] Afifi S. E., 1976, Surface Technology, V4, P173, DOI 10.1016/0376-4583(76)90026-1
[2] AHLBERG E, UNPUB
[3] AHLBERG E, IN PRESS ELECTROCHIM
[4] AZIM AAA, 1972, CORROS SCI, V12, P603
[5] AZIM AAA, 1970, CORROS SCI, V10, P421
[6] Bode H., 1977, LEAD ACID BATTERIES
[7] COX PA, 1987, ELECTRONIC STRUCTURE
[8] DANIEL V, 1983, ELECTROCHIM ACTA, V28, P785
[9] FORMATION OF PLANT CELLS USING A NITRATE PROCESS
EDWARDS, WH
HAMPSON, NA
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1979, 9 (03) : 381 - 387
[10] THE FORMATION OF SOLUBLE PB(IV) AND PB(II) SPECIES IN THE REACTIONS OF THE PBSO4/PBO2 ELECTRODE
HAMEENOJA, E
LAITINEN, T
SUNDHOLM, G
[J]. ELECTROCHIMICA ACTA, 1987, 32 (01) : 187 - 189

← 1 2 →