FERROCENE DERIVATIVES .27. FERROCENYLDIMETHYLPHOSPHINE

被引：17

作者：

KNOX, GR

PAUSON, PL

WILLISON, D

机构：

[1] Department of Pure and Applied Chemistry, University of Strathclyde

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 08期

关键词：

D O I：

10.1021/om00044a038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An improved synthesis of ferrocenyldimethylphosphine, FcPMe2, is limited only by the unreliable literature procedure for preparlng precursor dichloroferrocenylphosphine, FcPCl2. The latter compound yields a crystalline copper(I) iodide complex on reaction with lithium dimethylcuprate. Methanolysis of FcPCl2 yields unstable dimethyl ferrocenylphosphonite, FcP(OMe)2, which is converted to methyl ferrocenylphosphinite, FcPH(O)OMe, on heating or chromatography.

引用

页码：2930 / 2933

页数：4

共 18 条

[1] FERROCENYL-SUBSTITUTED PHOSPHENIUM CATIONS AND PHOSPHIDE ANIONS [J].