ALUMINA CHLOROFORM-PROMOTED CONVERSION OF THE RUTHENACYCLES [RU(CH2CME2CH2)(ETA-6-C6ME6)(PRPH2)] (R = ME OR PH) INTO THE CHLOROORTHOMETALLATED DERIVATIVES [RU(C6H4PRPH)CL(ETA-6-C6ME6)]

被引：8

作者：

ADOVASIO, V ^{[1
]}

DIVERSI, P ^{[1
]}

INGROSSO, G ^{[1
]}

LUCHERINI, A ^{[1
]}

MARCHETTI, F ^{[1
]}

NARDELLI, M ^{[1
]}

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 23期

关键词：

D O I：

10.1039/dt9920003385

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Interaction of the ruthenacyclobutanes [Ru(CH2CMe2CH2)(eta6-C6Me6)(PRPh2)] (R = Me 1 or Ph 3) with neutral alumina causes the decomposition of the metallacyclic moiety, with the formation of 1,1-dimethylcyclopropane, neopentane and alumina-adsorbed metal complexes which lead to the corresponding chloro orthometallated compounds [Ru(C6H4PRPh)CI(eta6-C6Me6)] (R - Me 2 or Ph 4) by reaction with CHCl3. The X-ray crystal structure of complex 2 reveals the presence of clathrated benzene. Crystal data: space group P2(1)/c, a = 14.068(14), b = 15.392(13), c = 13.064(14) angstrom, beta = 116.38(6)-degrees, Z = 4, R = 0.0510.

引用

页码：3385 / 3390

页数：6

共 21 条

[1] [Anonymous], 1974, INT TABLES XRAY CRYS, VIV
[2] ETA-6-ARENE-STABILIZED RUTHENACYCLOPENTANES - SYNTHESIS, X-RAY STRUCTURES, AND REACTION WITH THE TRITYL CATION
BARABOTTI, P
DIVERSI, P
INGROSSO, G
LUCHERINI, A
MARCHETTI, F
SAGRAMORA, L
ADOVASIO, V
NARDELLI, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (01): : 179 - 186
[3] CYCLOMETALLATION OF PHENYLPHOSPHINE AND NEOPENTYL LIGANDS IN RUTHENIUM(II) COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURE OF THE ORTHOMETALLATED COMPLEXES [RU(C6H4PR1R2)(CH2CME3)-(ETA-6-C6ME6)](R1 = R2 = PH-R1 = ME,R2 = PH-R1 = R2 = ME) AND OF THE METALLACYCLOBUTANES [RU(CH2CME2CH2)(ETA-C6ME6)-(PPHR1R2)] (R1 = R2 = PH-R1 = ME,R2 = PH)
DIVERSI, P
INGROSSO, G
LUCHERINI, A
MARCHETTI, F
ADOVASIO, V
NARDELLI, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (02): : 203 - 213
[4] REACTIONS OF RUTHENIUM(II)-CO-ORDINATED PHENYL PHOSPHINES - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF THE ORTHOMETALLATED COMPLEXES [RU(C6H4PR1R2)(CH2SIME3)(ETA-6-C6ME6)] (R1 = R2 = PH, R1 = PH, R2 = ME, R1 = R2 = ME) AND OF [(RU(CH2SIME3)2(MU-SIGMA,ETA-6-PME2PH))2] CONTAINING BRIDGING DIMETHYLPHENYLPHOSPHINE LIGANDS
DIVERSI, P
INGROSSO, G
LUCHERINI, A
MARCHETTI, F
ADOVASIO, V
NARDELLI, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (06): : 1779 - 1792
[5] COMPLEXES OF IRIDIUM(III) AND RHODIUM(III) WITH METALATED AND UNMETALATED DIMETHYL(1-NAPHTHYL)-PHOSPHINE AND METHYLPHENYL(1-NAPHTHYL)-PHOSPHINE
DUFF, JM
SHAW, BL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (20): : 2219 - &
[6] NON-RIGID-BODY THERMAL-MOTION ANALYSIS
DUNITZ, JD
WHITE, DNJ
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1973, 29 (JAN1): : 93 - 94
[7] ACTIVATION OF C-H-BONDS IN SATURATED-HYDROCARBONS ON PHOTOLYSIS OF (ETA-5-C5ME5)(PME3)IRH2 - RELATIVE RATES OF REACTION OF THE INTERMEDIATE WITH DIFFERENT TYPES OF C-H-BONDS AND FUNCTIONALIZATION OF THE METAL-BOUND ALKYL-GROUPS
JANOWICZ, AH
BERGMAN, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (12) : 3929 - 3939
[8] JOHNSON CK, 1965, ORNL3794 REP
[9] SURFACE-BOUND METAL HYDROCARBYLS - ORGANOMETALLIC CONNECTIONS BETWEEN HETEROGENEOUS AND HOMOGENEOUS CATALYSIS
MARKS, TJ
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (02) : 57 - 65
[10] MIRSKY K, 1978, COMPUTING CRYSTALLOG, P169

← 1 2 3 →