CHIRAL RECOGNITION AMONG TRISDIIMINE-METAL COMPLEXES .3. ADSORPTION OF TRIS-(3,3'-BI-1,2,4-TRIAZINE)IRON(II) COMPLEXES ONTO MONTMORILLONITE

被引：4

作者：

BREU, J

RANGE, KJ

机构：

来源：

MONATSHEFTE FUR CHEMIE | 1994年 / 125卷 / 02期

关键词：

CHIRAL RECOGNITION; CHIRAL DISCRIMINATION; SMECTITE; CLAY MINERALS; SURFACE CHARGE; INTERCALATION; ADSORPTION CAPACITIES; DIFFRACTION PATTERNS; TRISDIIMINE COMPLEXES;

D O I：

10.1007/BF00818162

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Adsorption isotherms of tris-(3,3'-bi-1,2,4-triazine)iron(II) complexes onto a well characterized montmorillonite are discussed in respect to the relative charge densities of adsorbent and adsorbat. While the adsorption capacities for trisbipyridyl and trisphenanthroline complexes differ for the racemates and the enantiomers they are equal for these complexes. Adsorption is limited to a monolayer. This backs the proposal that the observed chiral recognition phenomena are founded solely in the lateral interactions between adsorbats.

引用

页码：153 / 165

页数：13

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