PHOSPHINE-SUBSTITUTED SILSESQUIOXANES AS BUILDING-BLOCKS FOR ORGANOMETALLIC GELS

被引：23

作者：

FEHER, FJ

SCHWAB, JJ

PHILLIPS, SH

EKLUND, A

MARTINEZ, E

机构：

[1] Department of Chemistry, University of California, Irvine

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 10期

关键词：

D O I：

10.1021/om00010a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new approach is described for the preparation of organometallic gels containing large amounts of potentially catalytically active metal centers. This approach uses nonchelating, phosphine-substituted silsesquioxane frameworks as rigid spacers to connect phosphine complexes of late transition metals. The synthesis, characterization, and reactivity of an organometallic gel obtained from the reaction of 5 with [Rh(CO)(2)Cl](2) (2 P/Rh) are described.

引用

页码：4452 / 4453

页数：2

共 35 条

[1] FACILE, HIGH-YIELD SYNTHESIS OF FUNCTIONALIZED SPHEROSILICATES - PRECURSORS OF NOVEL ORGANOLITHIC MACROMOLECULAR MATERIALS
AGASKAR, PA
[J]. INORGANIC CHEMISTRY, 1990, 29 (09) : 1603 - 1603
[2] FUNCTIONALIZED SPHEROSILICATES - SOLUBLE PRECURSORS OF INORGANIC ORGANIC HYBRID MATERIALS
AGASKAR, PA
[J]. COLLOIDS AND SURFACES, 1992, 63 (1-2): : 131 - 138
[3] HETEROGENIZING HOMOGENEOUS CATALYSTS
BAILAR, JC
[J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1974, 10 (01): : 17 - 36
[4] SELECTIVE REDUCTIONS .X. REACTION OF ALUMINUM HYDRIDE WITH SELECTED ORGANIC COMPOUNDS CONTAINING REPRESENTATIVE FUNCTIONAL GROUPS . COMPARISON OF REDUCING CHARACTERISTICS OF LITHIUM ALUMINUM HYDRIDE AND ITS DERIVATIVES
BROWN, HC
YOON, NM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (07) : 1464 - &
[5] BURGY H, 1991, CHIMIA, V45, P3
[6] Chauvin Y., 1977, PROGR POLYMER SCI, V5, P95
[7] COLLMAN JP, 1987, PRINCIPLES APPLICATI
[8] MOLECULAR BUILDING-BLOCKS FOR THE SYNTHESIS OF CERAMIC MATERIALS - [SI8O12](OCH3)8
DAY, VW
KLEMPERER, WG
MAINZ, VV
MILLAR, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) : 8262 - 8264
[9] PHOSPHORUS(III)-CONTAINING SILICATES VIA A NEW APROTIC BUILDING-BLOCK APPROACH TO MULTICOMPONENT SILICATES
FEHER, FJ
WELLER, KJ
[J]. CHEMISTRY OF MATERIALS, 1994, 6 (01) : 7 - 9
[10] SYNTHESES OF HIGHLY-FUNCTIONALIZED POLYHEDRAL OLIGOSILSESQUIOXANES
FEHER, FJ
BUDZICHOWSKI, TA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 379 (1-2) : 33 - 40

← 1 2 3 4 →