MICROWAVE-HYDROTHERMAL PROCESSING OF METAL POWDERS

被引:104
作者
KOMARNENI, S [1 ]
PIDUGU, R [1 ]
LI, QH [1 ]
ROY, R [1 ]
机构
[1] PENN STATE UNIV,DEPT AGRON,UNIVERSITY PK,PA 16802
关键词
D O I
10.1557/JMR.1995.1687
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Novel microwave-hydrothermal processing has been developed by us recently for the synthesis of a wide variety of ceramic powders. Herein, we report the use of microwave-hydrothermal processing to synthesize several metal powders such as Cu, Ni, Co, and Ag by reducing their corresponding metal salts or hydroxides with ethylene glycol. Metal powders have been produced extremely rapidly a (few minutes) by microwave catalysis. The kinetics of metal powder synthesis have been increased by at least an order of magnitude by microwave-hydrothermal processing compared to the conventional refluxing process in ethylene glycol at about 195 degrees C.
引用
收藏
页码:1687 / 1692
页数:6
相关论文
共 33 条
[1]  
Barrer R. M., 1982, HYDROTHERMAL CHEM ZE, P360
[2]   HYDROCHEMICAL PREPARATION OF FINE PRECIOUS METAL POWDERS [J].
DEMOPOULOS, GP ;
POUSKOULELI, G .
JOURNAL OF METALS, 1988, 40 (06) :46-50
[3]  
FERRIER GG, 1985, PLATIN MET REV, V29, P175
[4]  
Fievet F., 1989, MRS BULL, V14, P29, DOI [10.1557/S0883769400060930, DOI 10.1557/S0883769400060930]
[5]  
FIGLARZ M, 1989, MATER RES SOC S P, V3, P125
[6]   MICROWAVE DISSOLUTION OF GEOLOGIC MATERIAL - APPLICATION TO ISOTOPE-DILUTION ANALYSIS [J].
FISCHER, LB .
ANALYTICAL CHEMISTRY, 1986, 58 (01) :261-263
[7]   FORMATION OF CARBON-FILMS ON CARBIDES UNDER HYDROTHERMAL CONDITIONS [J].
GOGOTSI, YG ;
YOSHIMURA, M .
NATURE, 1994, 367 (6464) :628-630
[8]   ELECTROLYTIC SYNTHESIS OF KAOLINITE UNDER HYDROTHERMAL CONDITIONS [J].
HAWKINS, DB ;
ROY, R .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1962, 45 (10) :507-508
[9]   PREPARATION OF TETRAGONAL BARIUM-TITANATE THIN-FILM ON TITANIUM METAL-SUBSTRATE BY HYDROTHERMAL METHOD [J].
KAJIYOSHI, K ;
ISHIZAWA, N ;
YOSHIMURA, M .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (02) :369-374
[10]  
Kalousek G. L., 1954, J AM CONCRETE I, V26, P233