EFFECT OF THE NONUNIFORM DEALUMINATION ON THE ACIDITY AND CATALYTIC ACTIVITY OF FAUJASITE

被引:26
作者
CORMA, A
MELO, FV
RAWLENCE, DJ
机构
[1] CSIC,INST CATALISIS & PETROLEOQUIM,SERRANO 119,E-28006 MADRID,SPAIN
[2] UNIV POLITECN VALENCIA,CSIC,INST TECNOL QUIM,VALENCIA,SPAIN
[3] JOSEPH CROSFIELD & LTD,CROSFIELD CATALYSIS,WARRINGTON,CHESHIRE,ENGLAND
来源
ZEOLITES | 1990年 / 10卷 / 07期
关键词
acid site distribution; dealumination; Faujasite;
D O I
10.1016/0144-2449(90)90081-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Theoretical models are used to simulate aluminum distribution in a Y zeolite crystal when an aluminum gradient along the crystal is produced by dealumination. From these models, the theoretical distribution of different types of acid sites is calculated. The effect of the aluminum gradient along the crystal on the acid site distribution is discussed, and it can be related with the differences observed in cracking activity when the Y zeolite is dealuminated by different procedures. © 1990.
引用
收藏
页码:690 / 694
页数:5
相关论文
共 23 条
[1]  
AKPORIAYE D, 1986, 7TH P INT C ZEOL TOK, P351
[2]   INFLUENCE OF FRAMEWORK ALUMINUM GRADIENTS ON THE CATALYTIC ACTIVITY OF Y-ZEOLITES - CRACKING OF GAS-OIL ON Y-ZEOLITES DEALUMINATED BY DIFFERENT PROCEDURES [J].
ARRIBAS, J ;
CORMA, A ;
FORNES, V ;
MELO, F .
JOURNAL OF CATALYSIS, 1987, 108 (01) :135-142
[3]   ALUMINUM DISTRIBUTION AND PROPERTIES OF FAUJASITES - BASIS OF MODELS AND ZEOLITE ACIDITY [J].
BEAGLEY, B ;
DWYER, J ;
FITCH, FR ;
MANN, R ;
WALTERS, J .
JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (09) :1744-1751
[4]   DETERMINATION OF PROTON ACIDITY OF SOLID CATALYSTS BY CHROMATOGRAPHIC ADSORPTION OF STERICALLY HINDERED AMINES [J].
BENESI, HA .
JOURNAL OF CATALYSIS, 1973, 28 (01) :176-178
[5]   ALUMINUM INSERTION INTO HIGH SILICA ZEOLITE FRAMEWORKS .1. REACTION WITH ALUMINUM HALIDES [J].
CHANG, CD ;
CHU, CTW ;
MIALE, JN ;
BRIDGER, RF ;
CALVERT, RB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (26) :8143-8146
[6]   COMPARISON OF THE INFORMATION GIVEN BY AMMONIA TPD AND PYRIDINE ADSORPTION - DESORPTION ON THE ACIDITY OF DEALUMINATED HY AND LAHY ZEOLITE CRACKING CATALYSTS [J].
CORMA, A ;
FORNES, V ;
MELO, FV ;
HERRERO, J .
ZEOLITES, 1987, 7 (06) :559-563
[7]  
CORMA A, 1988, ACS SYM SER, V368, P542
[8]  
Corma A., 1987, PREPR AM CHEM SOC DI, V32, P639
[9]  
Corma A., 1988, STUDIES SURFACE SCI, V37, P495
[10]  
DEMPSEY E, 1967, MOL SIEVES, P293