MODELING THE PRECIPITATION OF COPPER OXALATE AGGREGATES

被引:24
作者
DIRKSEN, JA
BENJELLOUN, S
RING, TA
机构
[1] Powder Technology Laboratory (LTP), Swiss Federal Institute of Technology
关键词
atomistic growth; batch reactor; Copper oxalate; mathematical model; particle aggregation;
D O I
10.1007/BF01410964
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The precipitation of copper oxalate has been studied in a batch reactor. Like many other systems, the morphology of these particles suggests that they were formed by an aggregation mechanism. A mathematical model has been developed to predict particle-size distributions grown in a batch reactor, which accounts for growth by two competing mechanisms, i.e., atomistic growth and particle aggregation. The results of this model are in good agreement with experimental observations for the precipitation of copper oxalate aggregates and other spherical aggregation systems cited in the literature. © 1990 Steinkopff.
引用
收藏
页码:864 / 876
页数:13
相关论文
共 22 条
[1]  
AOKI M, 1987, ADV CERAM MATER, V2, pA3
[2]   ALUMINUM HYDROUS OXIDE SOLS .1. SPHERICAL-PARTICLES OF NARROW SIZE DISTRIBUTION [J].
BRACE, R ;
MATIJEVI.E .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1973, 35 (11) :3691-3705
[3]   PREPARATION AND PARTICLE SIZE ANALYSIS OF CHROMIUM HYDROXIDE HYDROSOLS OF NARROW SIZE DISTRIBUTIONS [J].
DEMCHAK, R ;
MATIJEVI.E .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1969, 31 (02) :257-&
[4]  
DIRKSEN JA, 1989, IN PRESS J AM CE FAL
[5]   A new determination of the molecular dimensions [J].
Einstein, A .
ANNALEN DER PHYSIK, 1906, 19 (02) :289-306
[6]   HOMOGENEOUS PRECIPITATION OF SPHERICAL COLLOIDAL BARIUM-TITANATE PARTICLES [J].
GHERARDI, P ;
MATIJEVIC, E .
COLLOIDS AND SURFACES, 1988, 32 (3-4) :257-274
[7]   PREPARATION AND PROPERTIES OF MONODISPERSED COLLOIDAL PARTICLES OF LANTHANIDE COMPOUNDS .2. CERIUM(IV) [J].
HSU, WP ;
RONNQUIST, L ;
MATIJEVIC, E .
LANGMUIR, 1988, 4 (01) :31-37
[8]   PREPARATION AND PROPERTIES OF UNIFORM COLLOIDAL METAL PHOSPHATES .3. COBALT(II) PHOSPHATE [J].
ISHIKAWA, T ;
MATIJEVIC, E .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1988, 123 (01) :122-128
[9]  
Ives K. J., 1978, SCI BASIS FLOCCULATI
[10]   NUCLEATION AND GROWTH OF MONOSIZED TIO2 POWDERS FROM ALCOHOL SOLUTION [J].
JEAN, JH ;
RING, TA .
LANGMUIR, 1986, 2 (02) :251-255