FORMATION OF NOVEL 1-2 ADDUCTS BETWEEN BUN3P.CS2 AND ELECTRON-DEFICIENT ALKYNES

被引：20

作者：

AITKEN, RA ^{[1
]}

RAUT, SV ^{[1
]}

FERGUSON, G ^{[1
]}

机构：

[1] UNIV GUELPH,DEPT CHEM & BIOCHEM,GUELPH N1G 2W1,ONTARIO,CANADA

来源：

TETRAHEDRON | 1992年 / 48卷 / 37期

关键词：

D O I：

10.1016/S0040-4020(01)80474-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The zwitterionic adduct between tri-n-butylphosphine and carbon disulphide reacts under neutral conditions with two equivalents of dimethyl- and diethyl acetylenedicarboxylate, dibenzoylacetylene and methyl benzoylpropiolate to give novel crystalline dithiole-containing phosphorus ylides. An X-ray structure, spectroscopic and chemical properties all show these to be significantly stabilised by delocalisation.

引用

页码：8023 / 8030

页数：8

共 23 条

[1] FORMATION OF NOVEL-1-2 ADDUCTS BETWEEN BUN3P.CS2 AND ELECTRON-DEFICIENT ALKYNES
AITKEN, RA
FERGUSON, G
RAUT, SV
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[2] AITKEN RA, UNPUB TETRAHEDRON LE
[3] Aitken Rob, UNPUB
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[8] Tertiary phosphines containing the n-butyl radical.
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[9] 2-BENZYLIDENE-1,3-DITHIOLES - REMARKABLY RAPID WITTIG REACTION
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (19) : 4961 - &
[10] ADDITIONS OF A PHOSPHORANE TO DIMETHYL ACETYLENEDICARBOXYLATE
HENDRICK.JB
HALL, C
REES, R
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