FORMATION OF 1/1-COMPLEX, 2/1-COMPLEX, AND 2/2-COMPLEX BETWEEN CARBONYL-COMPOUNDS AND TITANIUM TETRACHLORIDE - AN AB-INITIO STUDY

被引：3

作者：

BRANCHADELL, V

OLIVA, A

机构：

[1] Department de Química, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 13期

关键词：

D O I：

10.1021/ic00117a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes of formaldehyde, acetaldehyde, and acetone with titanium tetrachloride of stoichiometries 1:1, 2:1, and 2:2 have been studied with ab initio SCF-MO methods. The competition between the formation of the 2:1 and 2:2 complexes has been analyzed, and the role of the steric effects has been discussed.

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页码：3433 / 3439

页数：7

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