TOWARDS MOLECULAR ELECTRONICS - A NEW FAMILY OF AROMATIC POLYIMINE CHELATES SUBSTITUTED WITH ALKYNE GROUPS

被引：84

作者：

SUFFERT, J ^{[1
]}

ZIESSEL, R ^{[1
]}

机构：

[1] EHICS,DEPT SCI MAT,F-67000 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 06期

关键词：

D O I：

10.1016/S0040-4039(00)74877-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bromo and chloro polyimines react with trimethylsilylacetylene in the presence of Pd(PPh3)2Cl2/CuI and diisopropylamine to give new substituted polyimines 1a to 8a. These compounds are deprotected with K2CO3 in MeOH/THF to produce the corresponding terminal alkynes 1b to 8b.

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页码：757 / 760

页数：4

相关论文

共 27 条

[1] FACILE SYNTHESIS OF ETHYNYLATED BENZOIC-ACID DERIVATIVES AND AROMATIC-COMPOUNDS VIA ETHYNYLTRIMETHYLSILANE [J].

AUSTIN, WB ;

BILOW, N ;

KELLEGHAN, WJ ;

LAU, KSY .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (11) :2280-2286

[2] NONLINEAR SUSCEPTIBILITIES OF FINITE CONJUGATED ORGANIC POLYMERS [J].

BERATAN, DN ;

ONUCHIC, JN ;

PERRY, JW .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (11) :2696-2698

[3]

BERLIN AA, 1966, J POLYM SCI C, V16, P369

[4]

Chodkiewicz W., 1957, ANN CHIM FRANCE, V2

[5] THE PREPARATION AND COORDINATION CHEMISTRY OF 2,2'-6',2''-TERPYRIDINE MACROCYCLES .1. [J].

CONSTABLE, EC ;

LEWIS, J .

POLYHEDRON, 1982, 1 (03) :303-306

[6] PHOTOCHROMIC HETEROCYCLIC FULGIDES .2. ELECTROCYCLIC REACTIONS OF (E)-ALPHA-2,5-DIMETHYL-3-FURYLETHYLIDENE(ALKYL-SUBSTITUTED METHYLENE)-SUCCINIC ANHYDRIDES [J].

DARCY, PJ ;

HELLER, HG ;

STRYDOM, PJ ;

WHITTALL, J .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1981, (01) :202-205

[7] PALLADIUM CATALYZED SYNTHESIS OF ARYL, HETEROCYCLIC AND VINYLIC ACETYLENE DERIVATIVES [J].

DIECK, HA ;

HECK, FR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 93 (02) :259-263

[8]

ELLIOTT G, 1973, CHEM BRIT, V9, P213

[9] ATTEMPTS TO FIND NEW ANTIMALARIALS .24. DERIVATIVES OF O-PHENANTHROLINE (7-8-3'-2'-PYRIDOQUINOLINE) [J].

HALCROW, BE ;

KERMACK, WO .

JOURNAL OF THE CHEMICAL SOCIETY, 1946, (MAR) :155-157

[10] PREPARATION AND PROPERTIES OF SOME TETRAKIS(METHYL CYANIDE)COPPER(I) COMPLEXES [J].

HATHAWAY, BJ ;

POSTLETHWAITE, JD ;

HOLAH, DG .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (AUG) :3215-+