REINVESTIGATION OF THE ELECTRONIC-SPECTRUM OF THE PHENYLNITRENE RADICAL

被引：26

作者：

CULLIN, DW ^{[1
]}

YU, L ^{[1
]}

WILLIAMSON, JM ^{[1
]}

PLATZ, MS ^{[1
]}

MILLER, TA ^{[1
]}

机构：

[1] OHIO STATE UNIV,DEPT CHEM,LASER SPECTR FACIL,120 W 18TH AVE,COLUMBUS,OH 43210

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 09期

关键词：

D O I：

10.1021/j100372a010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The origin band of the electronic transition long attributed to gaseous triplet phenylnitrene has been investigated by using a very high resolution pulsed laser to interrogate molecules cooled in a supersonic jet. The observed rotational and spin structure of this band is inconsistent with simple ideas of triplet phenylnitrene's structure and spectra. Details of these inconsistencies are presented. A possible alternative carrier for the spectrum is presented. © 1990 American Chemical Society.

引用

页码：3387 / 3391

页数：5

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