INDUCTION PHENOMENA IN GAS HYDRATE NUCLEATION

被引:233
作者
NATARAJAN, V [1 ]
BISHNOI, PR [1 ]
KALOGERAKIS, N [1 ]
机构
[1] UNIV CALGARY,DEPT CHEM & CHEM ENGN,CALGARY T2N 1N4,ALBERTA,CANADA
基金
加拿大自然科学与工程研究理事会;
关键词
D O I
10.1016/0009-2509(94)E0026-M
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The induction phenomena in hydrate nucleation have been investigated experimentally and the induction period data are reported for methane, ethane and carbon dioxide hydrates. Based on crystallization considerations, the metastable region for hydrate nucleation is discussed and the driving force for hydrate nucleation is defined. The induction period data for the various hydrates from a total of 93 hydrate formation runs were modelled as a function of the nucleation driving force.
引用
收藏
页码:2075 / 2087
页数:13
相关论文
共 97 条
[1]   HEATS OF SOLUTION OF ALCOHOLS IN WATER [J].
ALEXANDER, DM ;
HILL, DJT .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1969, 22 (02) :347-+
[2]  
ANDERSON FE, 1986, AICHE J, V32, P1231
[3]  
[Anonymous], 1959, HYDROGEN BONDING
[4]   HEAT CAPACITIES OF ORGANIC COMPOUNDS IN SOLUTION .I. LOW MOLECULAR WEIGHT ALCOHOLS IN WATER [J].
ARNETT, EM ;
KOVER, WB ;
CARTER, JV .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (15) :4028-&
[5]   GAS HYDRATES CONTAINING ARGON KRYPTON AND XENON - KINETICS AND ENERGETICS OF FORMATION AND EQUILIBRIA [J].
BARRER, RM ;
EDGE, AVJ .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1967, 300 (1460) :1-&
[6]  
Berecz E., 1983, STUDIES INORGANIC CH
[7]   NUCLEAR MAGNETIC RESONANCE STUDY OF COLLAGEN HYDRATION [J].
BERENDSEN, HJC .
JOURNAL OF CHEMICAL PHYSICS, 1962, 36 (12) :3297-&
[8]  
Bishnoi P.R., 1985, KINETICS FORMATION D
[9]  
Bishnoi P. R., 1986, KINETICS FORMATION D
[10]   MULTIPHASE EQUILIBRIUM FLASH CALCULATIONS FOR SYSTEMS CONTAINING GAS HYDRATES [J].
BISHNOI, PR ;
GUPTA, AK ;
ENGLEZOS, P ;
KALOGERAKIS, N .
FLUID PHASE EQUILIBRIA, 1989, 53 :97-104