NEW POLYMER ARCHITECTURES - POLYROTAXANES

被引：31

作者：

GIBSON, HW

BHEDA, M

ENGEN, PT

SHEN, YX

SZE, J

WU, C

JOARDAR, S

WARD, TC

LECAVALIER, PR

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,NATL SCI FDN,BLACKSBURG,VA 24061

[2] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1991年 / 42-3卷

关键词：

D O I：

10.1002/masy.19910420133

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Our objective is to prepare polymeric rotaxanes, materials in which many macrocycles are threaded by a linear macromolecule, in quantities sufficient to investigate the unique properties that we expect this unusual supramolecular architecture to confer. The design and synthesis of the macrocyclic components, "blocking groups" to constrain the macrocycles, and the polyrotaxanes are described. Model monomeric system has been synthesized and studied to ascertain their conformation. Step growth and chain growth approaches are described.

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页码：395 / 407

页数：13

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