THE FIRST REPORTED STRUCTURE OF A PLATINUM(IV) COMPLEX CONTAINING DEPROTONATED AMIDE LIGANDS - A MODEL FOR PLATINUM(IV)-PEPTIDE PROTEIN INTERACTIONS

被引：8

作者：

CAMPBELL, CJ

CASTINEIRAS, A

NOLAN, KB

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,E-15706 SANTIAGO,SPAIN

[2] ROYAL COLL SURGEONS IRELAND,DEPT CHEM,DUBLIN 2,IRELAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 19期

关键词：

D O I：

10.1039/c39950001939

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 1,2-diaminoethane-N,N,N',N'-tetra(N-methylacetamide) L with K-2[PtCl4] in aqueous solution gave H(2)L[PtCl4] acid the unexpected product cis-Pt(LH(-2))Cl-2 which is the first reported structure of a platinum (IV) complex containing deprotonated amide ligands and a model for platinum (IV)-peptide/protein interactions.

引用

页码：1939 / 1940

页数：2

共 14 条

[1] REACTIONS OF THE CIS-DIAMMINEDIAQUAPLATINUM(II) CATION WITH GLYCINAMIDE, N-GLYCYLGLYCINE, AND N-(N-GLYCYLGLYCYL)GLYCINE - CRYSTAL-STRUCTURE OF A COMPLEX WITH 2 DIAMMINEPLATINUM(II) CATIONS BOUND TO GLYCYLGLYCINATE [J].