NEW ONE-POT SYNTHESIS OF ALKYL NITRATES FROM ALCOHOLS

被引:17
作者
CASTEDO, L
MARCOS, CF
MONTEAGUDO, M
TOJO, G
机构
[1] UNIV SANTIAGO DE COMPOSTELA,FAC QUIM,DEPT QUIM ORGAN,SANTIAGO,SPAIN
[2] UNIV SANTIAGO DE COMPOSTELA,FAC QUIM,CSIC,SECC ALCALOIDES,SANTIAGO,SPAIN
关键词
D O I
10.1080/00397919208019268
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Treatment of alcohols with Ph3P-I2-imidazole followed by ''in situ'' reaction of the generated iodides with AgNO3 allows the mild conversion of alcohols into alkyl nitrates. Unlike previous procedures, this one requires no electrophilic nitrating conditions.
引用
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页码:677 / 681
页数:5
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