CYCLOMETALLATED COMPOUNDS OF PD(II) WITH BENZALAZINES

被引：14

作者：

CASAS, JL ^{[1
]}

GAYOSO, E ^{[1
]}

VILA, JM ^{[1
]}

PEREIRA, MT ^{[1
]}

GAYOSO, M ^{[1
]}

机构：

[1] UNIV SANTIAGO,DEPT INORGAN CHEM,E-15706 SANTIAGO,SPAIN

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1991年 / 21卷 / 02期

关键词：

D O I：

10.1080/15533179108020181

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of acetato and chloro bridged polymer cyclometallated compounds of Pd(II) with azines derived from 3,4-dimethoxybenzaldehyde and 3,4-methylenedioxobenzaldehyde is described. From the chloro bridged complexes the cyclometallated and non-cyclometallated monomers have been obtained by reaction of the former with triphenylphosphine. All the compounds have been fully characterized by elemental analyses as well as i.r. and H-1 n.m.r. spectroscopy.

引用

页码：263 / 273

页数：11

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