THE [3,3]-PHOSPHA-COPE REARRANGEMENT OF 1,2-DIVINYLPHOSPHIRANE COMPLEXES

被引：8

作者：

NGOC, HTH ^{[1
]}

MARINETTI, A ^{[1
]}

RICARD, L ^{[1
]}

MATHEY, F ^{[1
]}

机构：

[1] ECOLE POLYTECH,CHIM PHOSPHORE & MET TRANSIT LAB,CNRS,UM 13,F-91128 PALAISEAU,FRANCE

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 04期

关键词：

D O I：

10.1021/om00040a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of transient terminal vinylphosphinidene complexes with conjugated dienes leads to 3,4,7-trihydrophosphepine complexes via the [3,3]-phospha-Cope rearrangement of intermediate 1,2-divinylphosphirane complexes. The P = C double bond of the seven-membered ring reacts further with another molecule of diene to give the corresponding [2 + 4] cycloadduct.

引用

页码：1438 / 1439

页数：2

共 9 条

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