SOLUBLE PHTHALOCYANINES FOR THE DETECTION OF ORGANIC-SOLVENTS - THIN-FILM STRUCTURES WITH QUARTZ MICROBALANCE AND CAPACITANCE TRANSDUCERS

被引：48

作者：

OZTURK, ZZ

ZHOU, R

WEIMAR, U

AHSEN, V

BEKAROGLU, O

GOPEL, W

机构：

[1] UNIV TUBINGEN,CTR INTERFACE ANAL & SENSORS,D-72076 TUBINGEN,GERMANY

[2] TUBITAK,MARMARA RES CTR,GEBZE 41470,TURKEY

[3] ISTANBUL TECH UNIV,DEPT CHEM,ISTANBUL 80626,TURKEY

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 1995年 / 26卷 / 1-3期

关键词：

PHTHALOCYANINES; ORGANIC SOLVENTS; QUARTZ MICROBALANCE; CAPACITANCE TRANSDUCERS;

D O I：

10.1016/0925-4005(94)01588-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Soluble tetrakis-hexyl- and dodecylthiophthalocyaninatonickel(II) and the corresponding Pd(II) and Ag(I) complexes are investigated as sensitive materials for the detection of organic solvent vapors using quartz microbalance (QMB) and interdigital capacitance transducers (IDC). The results show that sensor responses were reversible at room temperature with response times in the order of several seconds depending on the partition coefficients of the organic solvents in the phthalocyanine film, which are correlated with the Ostwald solubility parameter and boiling temperature of the solvents investigated.

引用

页码：208 / 212

页数：5

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