A VERSATILE PREPARATIVE ROUTE TO 5-SUBSTITUTED-1,10-PHENANTHROLINE LIGANDS VIA 1,10-PHENANTHROLINE 5,6-EPOXIDE

被引：114

作者：

SHEN, YB ^{[1
]}

SULLIVAN, BP ^{[1
]}

机构：

[1] UNIV WYOMING,DEPT CHEM,LARAMIE,WY 82071

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 25期

关键词：

D O I：

10.1021/ic00129a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactive ligand 1,10-phenanthroline-5,6-epoxide is a versatile starting material for the preparation of a variety of 5-substituted-1, 10-phenanthroline ligands by reaction with oxygen-, carbon-, or nitrogen-based nucleophiles. All of the new ligands readily form complexes with the fac-Re-1(CO)(3)Cl fragment. Of particular interest are the syntheses of the amino and aminocrown derivatives of Re-1 which can function as cation sensors by perturbation of molecular luminescence. An interesting example involving Pb2+ is presented.

引用

页码：6235 / &

共 25 条

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