SYNTHESIS AND COMPLEXATION BEHAVIOR OF A DOUBLE-ARMED CROWN THIOETHER LIGAND

被引：6

作者：

NEVE, F

GHEDINI, M

机构：

[1] Dipartimento di Chimica, Università della Calabria, 1-87030 Arcavacata di Rende, CS

来源：

INORGANICA CHIMICA ACTA | 1994年 / 217卷 / 1-2期

关键词：

COPPER COMPLEXES; CROWN THIOETHER COMPLEXES;

D O I：

10.1016/0020-1693(93)03775-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel macrocycle 3,11-bis[4-(n-hexyloxy)benzoyloxy]-1,5,9,13-tetrathiacyclohexadecane (2) was obtained as a mixture of cis and trans isomers by reaction of 1,5,9,13,-tetrathiacyclohexadecane-3,11-diol (1) (cis and trans) and 4-(n-hexyloxy)benzoyl chloride. Ligand 2 readily reacts with [Cu(I)(MeCN)4]PF6 to afford the white, cationic complex [Cu(I)(2)]PF6, wherein 2 acts as a tetradentate donor. Polarising microscopy showed no mesomorphism of either 2 or the [Cu(I)(2)]PF6 species.

引用

页码：1 / 2

页数：2

共 16 条

[1] MESOMORPHIC STILBAZOLE COMPLEXES OF SILVER OCTYL SULFATE - CRYSTAL AND MOLECULAR-STRUCTURE OF BIS[4-(4-METHOXYSTYRYL)PYRIDINATO]SILVER(I) OCTYL SULFATE HEMIHYDRATE
ADAMS, H
BAILEY, NA
BRUCE, DW
DAVIS, SC
DUNMUR, DA
HEMPSTEAD, PD
HUDSON, SA
THORPE, S
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (04) : 395 - 400
[2] CHEMISTRY OF THIOETHER MACROCYCLIC COMPLEXES
Blake, Alexander J.
Schroeder, Martin
[J]. ADVANCES IN INORGANIC CHEMISTRY <D>, 1990, 35 : 1 - 80
[3] COOPER SR, 1990, STRUCT BOND, V72, P1
[4] TRANSITION-METAL LIQUID-CRYSTALS - ADVANCED MATERIALS WITHIN THE REACH OF THE COORDINATION CHEMIST
ESPINET, P
ESTERUELAS, MA
ORO, LA
SERRANO, JL
SOLA, E
[J]. COORDINATION CHEMISTRY REVIEWS, 1992, 117 : 215 - 274
[5] SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR CYCLOPALLADATED PARA-ALKOXYPHENYLAZO COMPLEXES - PREPARATION OF NEW MESOGENIC MATERIALS
GHEDINI, M
ARMENTANO, S
NEVE, F
LICOCCIA, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (06): : 1565 - 1567
[6] TRANSITION-METALS COMPLEXES TO ORDERED MESOPHASES - SYNTHESIS AND MESOMORPHIC PROPERTIES OF CYCLOPALLADATED COMPLEXES FORMED FROM P-ALKOXY-P'-ALKYL-AZOBENZENES
GHEDINI, M
ARMENTANO, S
NEVE, F
[J]. INORGANICA CHIMICA ACTA, 1987, 134 (01) : 23 - 24
[7] CYCLOPALLADATION OF 5-(1-HEXYL)-2([4'-(1-UNDECYLOXY)PHENYL])PYRIMIDINE - SYNTHESIS AND CHARACTERIZATION OF MONONUCLEAR COMPLEXES
GHEDINI, M
PUCCI, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 395 (01) : 105 - 112
[8] METALLOMESOGENS - METAL-COMPLEXES IN ORGANIZED FLUID PHASES
GIROUDGODQUIN, AM
MAITLIS, PM
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (04): : 375 - 402
[9] CALAMITIC METALLOMESOGENS - METAL-CONTAINING LIQUID-CRYSTALS WITH RODLIKE SHAPES
HUDSON, SA
MAITLIS, PM
[J]. CHEMICAL REVIEWS, 1993, 93 (03) : 861 - 885
[10] STRUCTURE AND MESOPHASES OF HEXACYCLEN DERIVATIVES
IDZIAK, SHJ
MALISZEWSKYJ, NC
HEINEY, PA
MCCAULEY, JP
SPRENGELER, PA
SMITH, AB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (20) : 7666 - 7672

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