PHOTOFRAGMENT-EXCITATION SPECTRUM OF NO2 OBSERVED THROUGH O(3PJ) DETECTION

被引：53

作者：

MIYAWAKI, J

YAMANOUCHI, K

TSUCHIYA, S

机构：

[1] Department of Pure and Applied Sciences, College of Arts and Sciences, The University of Tokyo, Meguro-ku, Tokyo, 153, Komaba

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 180卷 / 04期

关键词：

D O I：

10.1016/0009-2614(91)90321-Y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photodissociation dynamics of NO2 was investigated by observation of the photofragment-excitation (PHOFEX) spectrum of NO2 obtained by detecting O (3P j; J = 2, 1, and 0). Near the photodissociation threshold, the average branching ratios of three spin-orbit sublevels were consistent with those predicted by a restricted statistical distribution model, in which the predissociation rate to produce O atoms in each spin-orbit state is proportional to the limited number of energetically allowed states of the NO fragment.

引用

页码：287 / 292

页数：6

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