THE 1ST THERMALLY-INDUCED RETRO-OXY-COPE REARRANGEMENT

被引：13

作者：

ELMORE, SW ^{[1
]}

PAQUETTE, LA ^{[1
]}

机构：

[1] OHIO STATE UNIV,EVANS CHEM LABS,COLUMBUS,OH 43210

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 03期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)92617-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reversibility of the thermal oxy-Cope rearrangement is demonstrated with the specific example 10 reversible 11, and the pathway and energetics associated with this phenomenon are outlined.

引用

页码：319 / 322

页数：4

共 10 条

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[2]

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[3]

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[4]

PAQUETTE LA, 1990, SYNLETT, P67

[5] [3.3] SIGMATROPY WITHIN 1-VINYL-2-ALKENYL-7,7-DIMETHYL-EXO-NORBORNAN-2-OLS - THE 1ST ATROPSELECTIVE OXYANIONIC COPE REARRANGEMENT [J].

PAQUETTE, LA ;

PEGG, NA ;

TOOPS, D ;

MAYNARD, GD ;

ROGERS, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (01) :277-283

[6] BOAT CHAIR TOPOGRAPHIC STEREOSELECTION DURING ANIONIC OXY-COPE REARRANGEMENT OF 1-ALKENYL-2-CYCLOPENTENYL-ENDO-NORBORNAN-2-OLS [J].

PAQUETTE, LA ;

TELEHA, CA ;

TAYLOR, RT ;

MAYNARD, GD ;

ROGERS, RD ;

GALLUCCI, JC ;

SPRINGER, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (01) :265-277

[7] STEREOCONTROLLED CONSTRUCTION OF COMPLEX CYCLIC-KETONES VIA OXY-COPE REARRANGEMENT [J].

PAQUETTE, LA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (06) :609-626

[8]

PAQUETTE LA, UNPUB

[9]

WILSON SR, UNPUB ORG REACT

[10]

1988, CHEM DEP FELLOW

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