FAR-INFRARED SPECTROSCOPY OF THE ELECTRODE SOLUTION INTERFACE - VIBRATIONAL INTERACTION OF ADSORBED METAL ATOMS WITH SURFACE-STATES OF A GOLD ELECTRODE

被引：16

作者：

LI, J

PONS, S

SMITH, JJ

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

[2] OFF NAVAL RES,ARLINGTON,VA 22217

来源：

LANGMUIR | 1986年 / 2卷 / 03期

关键词：

ATOMS - Adsorption - GOLD AND ALLOYS - SPECTROSCOPY; INFRARED;

D O I：

10.1021/la00069a007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The direct observation of metal-metal vibrations at an electrode surface by infrared spectroelectrochemistry is reported and discussed. Far-infrared spectra of the lithium-gold, gold-gold, and lithium-lithium interactions at a gold electrode surface in lithium perchlorate solutions are presented. A mechanism for surface-induced dipole moments is discussed.

引用

页码：297 / 301

页数：5

共 18 条

[1]

Bewick A., 1985, ADV INFRARED RAMAN S, V12, P1

[2] SURFACE-STATES AT THE METAL-ELECTROLYTE INTERFACE [J].