INFRARED-LASER SPECTROSCOPY OF URACIL IN A PULSED SLIT JET

被引:46
作者
VIANT, MR
FELLERS, RS
MCLAUGHLIN, RP
SAYKALLY, RJ
机构
[1] Department of Chemistry, University of California, Berkeley
关键词
D O I
10.1063/1.469960
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new high-temperature pulsed slit jet source has enabled the first observation of a rotationally resolved vibrational spectrum of a nucleotide base. The spectrum, centered at 1703.888 cm(-1), has been assigned to the fundamental out-of-phase mixed carbonyl stretching vibration of the diketo tautomer of uracil, clarifying an ambiguous assignment from low-resolution studies. (C) 1995 American Institute of Physics.
引用
收藏
页码:9502 / 9505
页数:4
相关论文
共 33 条
[1]  
Watson J.D., Crick F.H.C., Nature, 171, (1953)
[2]  
Saykally R.J., Blake G.A., Science, 259, (1993)
[3]  
Brady B.B., Peteanu L.A., Levy D.H., Chem. Phys. Lett., 147, (1988)
[4]  
Brown R.D., Godfrey P.D., McNaughton D., Pierlot A.P., J. Am. Chem. Soc., 110, (1988)
[5]  
Brown R.D., Godfrey P.D., McNaughton D., Pierlot A.P., J. Chem. Soc. Chem. Commun, (1989)
[6]  
Brown R.D., Godfrey P.D., McNaughton D., Pierlot A.P., J. Am. Chem. Soc., 111, (1989)
[7]  
Brown R.D., Godfrey P.D., McNaughton D., Pierlot A.P., Chem. Phys. Lett., 156, (1989)
[8]  
Busarow K.L., Blake G.A., Laughlin K.B., Cohen R.C., Lee Y.T., Saykally R.J., J. Chem. Phys., 89, (1988)
[9]  
Nesbitt D.J., Annu. Rev. Phys. Chem., 45, (1994)
[10]  
Bardi G., Bencivenni L., Ferro D., Martini B., Nunziante-Cesaro S., Teghil R., Thermochim. Acta, 40, (1980)