GAS-PHASE THERMOLYSIS OF 6-CYCLOPROPYLPENTAFULVENES AND 6-OXIRANYLPENTAFULVENES - NOVEL ROUTES TO DIHYDROINDENES AND VINYLCYCLOPENTADIENES

被引：9

作者：

GRIESBECK, AG ^{[1
]}

PETERS, K ^{[1
]}

PETERS, EM ^{[1
]}

VONSCHNERING, HG ^{[1
]}

机构：

[1] MAX PLANCK INST FESTKORPERFORSCH,W-7000 STUTTGART 80,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 07期

关键词：

D O I：

10.1002/anie.199008031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In agreement with the results of MNDO calculations, 2 is predominantly formed as the most stable dihydroindene isomer when the cyclopropylpentafulvene 1 (X = CH2) undergoes thermolysis in the gas phase. The analogous 6‐oxi‐ranylpentafulvene 1 (X = O) eliminates carbon monoxide under the same conditions and affords the vinylcyclopentadiene isomer 3 in high yield. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：803 / 805

页数：3

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