RAMAN-SPECTROSCOPIC EVIDENCE FOR 4-FOLD COORDINATED TITANIUM IN SILICALITE-I

被引：18

作者：

PILZ, W ^{[1
]}

PEUKER, C ^{[1
]}

TUAN, VA ^{[1
]}

FRICKE, R ^{[1
]}

KOSSLICK, H ^{[1
]}

机构：

[1] ZENTRUM HETEROGENE KATALYSE,D-12484 BERLIN ALDERSHOF,GERMANY

来源：

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1993年 / 97卷 / 08期

关键词：

SPECTROSCOPY; RAMAN; TI-ZSM-5; ZEOLITES;

D O I：

10.1002/bbpc.19930970813

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Raman spectroscopic investigations reveal the synthesis of Ti-Silicalite I with four-fold coordinated titanium. A new Raman band at 960 cm-1 assigned to tetrahedrally coordinated titanium in the SiO2 matrix is found. Non-framework TiO2 species containing octahedrally coordinated titanium could be also distinguished.

引用

页码：1037 / 1040

页数：4

共 17 条

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