HYDROPEROXIDATION IN THE LOW-TEMPERATURE THERMOOXIDATION OF LINEAR LOW-DENSITY POLYETHYLENE

被引：10

作者：

FANTON, E ^{[1
]}

TIDJANI, A ^{[1
]}

ARNAUD, R ^{[1
]}

机构：

[1] UNIV CLERMONT FERRAND,PHOTOCHIM MOLEC & MACROMOLEC LAB,CNRS,URA 433,F-63177 CLERMONT FERRAND,FRANCE

来源：

POLYMER | 1994年 / 35卷 / 02期

关键词：

HYDROPEROXIDATION; THERMOOXIDATION; LLDPE;

D O I：

10.1016/0032-3861(94)90715-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Thermooxidation at 80 degrees C of two types of low density polyethylene (ethylene-1-butene and ethylene-1-propene) was examined from i.r. spectroscopic measurements. The maximum concentration of isolated hydroperoxides was determined and compared with the initial content of vinyl and vinylidene unsaturations of the polymer films.

引用

页码：433 / 434

页数：2

共 4 条

[1]

ARNAUD R, 1984, MACROMOLECULES, V17, P332, DOI 10.1021/ma00133a012

[2] OCTENE-1 LINEAR LOW-DENSITY POLYETHYLENE PHOTOOXIDATION [J].

FANTON, E ;

PELLEREAU, B ;

ARNAUD, R ;

LEMAIRE, J .

POLYMER PHOTOCHEMISTRY, 1985, 6 (06) :437-451

[3] THERMOOXIDATIVE DEGRADATION OF POLYETHYLENE .1. .2. STRUCTURAL-CHANGES OCCURRING IN LOW-DENSITY POLYETHYLENE, HIGH-DENSITY POLYETHYLENE, AND TETRATETRACONTANE HEATED IN AIR [J].

HOLMSTROM, A ;

SORVIK, EM .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1978, 16 (10) :2555-2586

[4] GAMMA-OXIDATION OF LINEAR LOW-DENSITY POLYETHYLENES - ETHYLENE BUTENE AND ETHYLENE HEXENE COPOLYMERS [J].

TIDJANI, A ;

ARNAUD, R .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (03) :603-609

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