SALICYLATO (SAL) COMPLEXES OF 2ND-ROW AND 3RD-ROW TRANSITION-ELEMENTS, AND THE CRYSTAL-STRUCTURE OF [NME4]2[MOO2(SAL)2].2H2O

被引：29

作者：

EDWARDS, CF

GRIFFITH, WP

WHITE, AJP

WILLIAMS, DJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 24期

关键词：

D O I：

10.1039/dt9930003813

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Salts of [MO,L2]2- [M = Mo or Os; L = salicylate(2-) (sal), 4- or 5-methylsalicylate(2-)] and [M2O5(sal)2]2- (M = Mo or W) were prepared and their Raman, infrared, H-1 and C-13-{H-1} NMR and X-ray photoelectron spectra measured. The crystal structure of [NMe4]2[MoO2(sal)2]-2H2O has been determined. Vibrational, H-1 and C-13-{H-1} NMR spectra have also been recorded for the complexes [Pd(sal)2]2-, (Pd(Hsal)2] and [Rh2(Hsal)4(EtOH)(H2O)].EtOH.H2O.

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页码：3813 / 3819

页数：7

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