SYNTHESIS AND CRYSTAL-STRUCTURE OF BIS[(7,9-DIAZA-3,14-DITHIATETRACYCLE[15,4,0,0-4,0-5,0-13,0-14]NONACOSA-1(17),18,20,4(22),23,25,13(26),27,29-NONAENE)CHLOROCOPPER(II)] TETRACHLORODICUPRATE(I) BISMETHANOL - ATYPICAL NONPLANAR CONFORMATION OF THE [CU2CL4](2-) ANION

被引：8

作者：

ESCRICHE, L

LUCENA, N

CASABO, J

TEIXIDOR, F

KIVEKAS, R

SILLANPAA, R

机构：

[1] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 BARCELONA,SPAIN

[2] CSIC,INST CIENCIA MAT,E-08193 BARCELONA,SPAIN

[3] UNIV HELSINKI,DIV INORGAN CHEM,SF-00100 HELSINKI 10,FINLAND

[4] UNIV TURKU,DEPT CHEM,SF-20500 TURKU,FINLAND

来源：

POLYHEDRON | 1995年 / 14卷 / 05期

关键词：

D O I：

10.1016/0277-5387(94)00289-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A doubly complex salt containing the atypical non-planar Cu-1 dimeric anion [Cu2Cl4](2-) and a Cu-II containing macrocyclic cation has been synthesized starting from CuCl2 . 2H(2)O and a new N2S2 type macrocycle 7,9-diaza-3,1 4-dithiatetracycle [15,4,0,0(4,5),0(13,14)]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene. The structure of the complex was determined by X-ray crystallography.

引用

页码：649 / 654

页数：6

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