A KINETIC APPROACH TO THE NETWORK FORMATION IN AN ALTERNATING STEPWISE COPOLYMERIZATION

被引：35

作者：

GALINA, H ^{[1
]}

SZUSTALEWICZ, A ^{[1
]}

机构：

[1] UNIV WROCLAW,INST COMP SCI,PL-51151 WROCLAW,POLAND

来源：

MACROMOLECULES | 1990年 / 23卷 / 16期

关键词：

34;

D O I：

10.1021/ma00218a019

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A Smoluchowski-like coagulation equation is used for calculating the molecular size distribution in kinetically controlled stepwise copolymerization of 3- and 2-functional monomers up to the gel point. In the systems where the reactivities of functional groups are affected by the substitution effect, the present method predicts different distributions and gel point conversions than the cascade theory. © 1990, American Chemical Society. All rights reserved.

引用

页码：3833 / 3838

页数：6

共 42 条

[1] APPROXIMATE THEORIES OF GELATION [J].