CYCLING BEHAVIOR OF ELECTRODEPOSITED ZINC ALLOY ELECTRODE FOR SECONDARY LITHIUM BATTERIES

被引：42

作者：

FUJIEDA, T

TAKAHASHI, S

HIGUCHI, S

机构：

[1] Government Industrial Research Institute, Ikeda, Osaka

来源：

JOURNAL OF POWER SOURCES | 1992年 / 40卷 / 03期

关键词：

D O I：

10.1016/0378-7753(92)80016-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cycling behaviour of an electroplated lithium-zinc alloy film electrode is examined in 1 M LiClO4/propylene carbonate. The cycle life depends on the utilization of lithium in the alloy and is improved by dispersion of 2 to 4 wt.% iron. This improvement is more effective when the discharge cutoff potential is 0.5 V versus Li+/Li. In this case, the life cycle is about 150 cycles at 250 mA h g-1 of lithium utilization. The reason for improvement is possibly the suppression of electrode disintegration and the appropriate choice of alloy phases.

引用

页码：283 / 289

页数：7

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