HEATS OF HYDROGENATION .4. HOMOAROMATICITY IN NORCARADIENE AND CYCLOHEPTATRIENE

被引：42

作者：

ROTH, WR

KLARNER, FG

SIEPERT, G

LENNARTZ, HW

机构：

[1] Fakultät für Chemie, Universität Bochum, Bochum, W-4630

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 01期

关键词：

HOMOAROMATICITY; RESONANCE ENERGY; CALCULATIONS; FORCE-FIELD; HEATS OF HYDROGENATION;

D O I：

10.1002/cber.19921250134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By comparison of the heats of hydrogenation of fixed norcaradienes with analogous cyclobutane derivatives and from the difference of experimental heats of formation with values calculated by force-field methods the homoaromatic stabilization of norcaradienes and cycloheptatrienes are calculated and compared with the equilibrium position of the respective valence isomers.

引用

页码：217 / 224

页数：8

共 79 条

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