PRONOUNCED EFFECT OF INTERANNULAR TRIMETHYLENE BRIDGES ON THE RATE OF INTRAMOLECULAR ELECTRON-TRANSFER IN MIXED-VALENCE BIFERROCENIUM SALTS - A NOVEL ELECTRONIC GROUND-STATE OF FERROCENIUM CATIONS

被引：3

作者：

DONG, TY

LEE, TY

WEN, YS

LEE, SH

HSIEH, CF

LEE, GH

PENG, SM

机构：

[1] NATL CHUNGHSING UNIV,DEPT CHEM,TAICHUNG,TAIWAN

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI,TAIWAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 456卷 / 02期

关键词：

D O I：

10.1016/0022-328X(93)80432-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

X-ray structure determinations of two new constitutional isomers of biferrocene, the effects of interannular trimethylene bridges on intramolecular electron-transfer rates in the solid state, and characterization of the electronic ground state of a series of ferrocenium cations are reported.

引用

收藏

页码：239 / 242

页数：4

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