NOVEL HETEROCYCLES - 1,3,4-OXADITHIOLANE, 1,3,4-OXADISELENOLANE, 1,3-OXATHIETANE AND 1,3-OXASELENETANE DERIVATIVES

被引：18

作者：

ISHII, A ^{[1
]}

DING, MX ^{[1
]}

NAKAYAMA, J ^{[1
]}

HOSHINO, M ^{[1
]}

机构：

[1] SAITAMA UNIV,FAC SCI,DEPT CHEM,URAWA,SAITAMA 338,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the monohydrazone 1 of 2,2,4,4-tetramethyl-1,5-diphenylpentane-1,5-dione with S2Cl2 affords a bicyclic 1,3,4-oxadithiolane derivative 2, which gives an equilibrium mixture of a 1,3-oxathietane 7 and its ring-opened isomer 6 on treatment with P(NMe2)3, whilst the 1,3,4-oxadiselenolane 3 prepared from 1 and Se2Cl2 affords a 1,3-oxaselenetane 8 and a cyclic ketone 9 on treatment with the same reagent.

引用

页码：7 / 8

页数：2

共 12 条

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