AN EMISSION AND KINETIC-STUDY OF THE IMPURITY-TRAPPED EXCITON IN CDCL2-PB2+

被引:28
作者
MOINE, B [1 ]
PEDRINI, C [1 ]
GHIORDANESCU, V [1 ]
机构
[1] INST PHYS & TECHNOL MAT,BUCHAREST,ROMANIA
关键词
D O I
10.1088/0953-8984/6/22/008
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We have studied the spectroscopic properties of Pb2+ in a CdCl2 host crystal. By excitation in the absorption band due to the 1A1g --> 3T1u (P-3(1)) transition, two emission bands are observed. At very low temperature a strong uv luminescence with a very long lifetime (2.5 ms) is detected, As the temperature increases, the lifetime of the uv emission drastically decreases to a few nanoseconds at 100 K, and the uv intensity declines. Meanwhile a strong green fluorescence appears. It is assumed that this emission is of the impurity-trapped exciton type, as in the case of CdCl2:Cu+ and BaF2:Eu2+. A detailed study of the kinetics of both fluorescences is presented.
引用
收藏
页码:4093 / 4098
页数:6
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