STRUCTURE OF SODIUM-HYDROGEN (+)-TARTRATE MONOHYDRATE

被引：11

作者：

BOTT, RC ^{[1
]}

SAGATYS, DS ^{[1
]}

LYNCH, DE ^{[1
]}

SMITH, G ^{[1
]}

KENNARD, CHL ^{[1
]}

机构：

[1] UNIV QUEENSLAND,DEPT CHEM,BRISBANE 4072,AUSTRALIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192012605

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the title compound comprises a network polymer involving all tartrate O atoms (except the protonated carboxyl O atom) in bonding to four separate sodium complex centres. The water molecule completes a distorted bi-face capped trigonal prismatic eight coordination about Na [Na-O range 2.415-2.826 (2), mean 2.57 (14) angstrom] and is also involved in a number of hydrogen-bonding interactions. In this respect, the structure differs from the isomorphous series of anhydrous univalent cation (K+, Rb+, Cs+, Tl+, NH4+) salts of hydrogen (+)-tartrate.

引用

页码：1150 / 1152

页数：3

共 16 条

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