ALLYLIC DIBORANES

被引：19

作者：

BUBNOV, YN

机构：

[1] N.D.2elinsky Institute of Organic Chemistry, Academy of Sciences of the U. S. S. R., Moscow B-334

来源：

PURE AND APPLIED CHEMISTRY | 1991年 / 63卷 / 03期

关键词：

D O I：

10.1351/pac199163030361

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and chemical properties of a series of novel unsaturated diboranes 1-6 with both boron atoms in allylic positions are described. Some new reactions of allylboranes, presented in the second section, proceed either with rearrangement (2-pi+2-pi+2-sigma) or with retention of configuration of the allylic fragment. Convenient methods for the preparation of allyl- and diallyloxiranes, homoallylic alcohols and thiols, as well as an approach for designing cyclic structures via allylboranes are suggested.

引用

页码：361 / 364

页数：4

共 16 条

[1]

BOBNOV YN, 1989, IN PRESS IZV AN SS K, P210

[2] ALLYLBORANES - MOLECULAR DESIGN [J].

BUBNOV, YN .

PURE AND APPLIED CHEMISTRY, 1987, 59 (07) :895-906

[3]

BUBNOV YN, 1988, IAN SSSR KH, P1199

[4]

BUBNOV YN, 1990, IN PRESS IZV AN SS K

[5]

BUBNOV YN, 1987, IAN SSSR KH, P1193

[6]

BUBNOV YN, 1989, IAN SSSR KH, P1210

[7]

BUBNOV YN, 1988, IAN SSSR KH, P2184

[8]

BUBNOV YN, 1989, RUSS J ORGANOMETAL C, V2, P1433

[9]

GURSKY ME, 1990, IAN SSSR KH, P495

[10] A SIMPLE SYNTHESIS OF 3-BOROLENES - REPRESENTATION OF 1-PHENYL-3-BOROLENES [J].

HERBERICH, GE ;

HESSNER, B ;

SOHNEN, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 233 (03) :C35-C37

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