ASYMMETRIC OXIDATION OF SULFIDES BY CYCLOHEXANONE MONOOXYGENASE

被引：36

作者：

SECUNDO, F

CARREA, G

DALLAVALLE, S

FRANZOSI, G

机构：

[1] CNR,IST CHIM ORMONI,VIA MARIO BIANCO 9,I-20131 MILAN,ITALY

[2] CTR CNR,DIPARTIMENTO CHIM ORGAN & IND,MILAN,ITALY

[3] IST DONEGANI SPA,I-28100 NOVARA,ITALY

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 09期

关键词：

D O I：

10.1016/S0957-4166(00)82244-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclohexanone monooxygenase catalyzes the asymmetric oxidazion of numerous alkyl aryl sulfides with the alkyl chain functionalyzed with Cl, CN, vinyl or hydroxy groups. Sulfoxides with enantiomeric excesses up to 99% were obtained. The structure of the sulfide markedly influenced enzyme enantioselectivity.

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页码：1981 / 1982

页数：2

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