SPECTROSCOPIC EVIDENCE FOR THE REDOX REACTION BETWEEN COPPER(II) AND A PTERIN COFACTOR MODEL, 6,7-DIMETHYL-5,6,7,8-TETRAHYDROPTERIN

被引：14

作者：

FUNAHASHI, Y

KOHZUMA, T

ODANI, A

YAMAUCHI, O

机构：

[1] NAGOYA UNIV, FAC SCI, DEPT CHEM, NAGOYA 46401, JAPAN

[2] OSAKA UNIV, COLL GEN EDUC, INST CHEM, TOYONAKA, OSAKA 560, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 02期

关键词：

D O I：

10.1246/cl.1994.385

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of Cu(II) with 6,7-dimethyl-5,6,7,8-tetrahydropterin dihydrochloride (H(4)DMP.2HCl) in CH3OH-CH3CN have been investigated by spectroscopic methods. The redox reaction in the 1:1 Cu(II)-H(4)DMP.2HCl system has been established by detection of the protonated trihydropterin radical (H(4)DMP(.+))nd its disproportionation products.

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页码：385 / 388

页数：4

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