IRON-PROMOTED DEAMINATION REACTIONS OF N-SUBSTITUTED 7-AZANORBORNADIENE DERIVATIVES

被引：10

作者：

CHOW, TJ

HWANG, JJ

SUN, CH

DING, MF

机构：

[1] NATL CHUNG CHENG UNIV,DEPT CHEM,CHIAYI 621,TAIWAN

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 107,TAIWAN

[3] PROVIDENCE UNIV,DEPT APPL CHEM,TAICHUNG 433,TAIWAN

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 09期

关键词：

D O I：

10.1021/om00033a055

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Summary: Two types of metallic intermediates were observed in the iron-promoted deamination reactions of N-substituted 7-azanorbornadiene (ANBD) derivatives, i.e., (ANBD)Fe(CO)4 formed first, followed by (ANBD)-Fe(CO)3. The latter can also be prepared alternatively from the former by reacting with trimethylamine N-oxide. Their spectroscopic characteristics as well as their roles in the deamination mechanisms were analyzed.

引用

页码：3762 / 3765

页数：4

共 7 条

[1] A STEREOSPECIFIC DIMERIZATION OF NORBORNADIENE DERIVATIVES AND THE CRYSTAL-STRUCTURE OF HEPTACYCLO[6.6.0.02,6.03,13.04,11.05,9.010,14]TETRADECANE [J].