BIOTRANSFORMATION OF ALKENES BY HALOPEROXIDASES - REGIOSPECIFIC BROMOHYDRIN FORMATION FROM CINNAMYL SUBSTRATES

被引：24

作者：

COUGHLIN, P ^{[1
]}

ROBERTS, S ^{[1
]}

RUSH, C ^{[1
]}

WILLETTS, A ^{[1
]}

机构：

[1] UNIV EXETER,DEPT BIOL SCI,EXETER EX4 4QG,DEVON,ENGLAND

来源：

BIOTECHNOLOGY LETTERS | 1993年 / 15卷 / 09期

关键词：

D O I：

10.1007/BF00131755

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

A study of bromohydrin formation from some cinnamyl substrates by the heme-dependent chloroperoxidase from Caldariomyces fumago has identified differences in the regio- and diastereospecificity of this enzyme relative to chemical hydrobromination. Diastereospecificity of bromohydrin formation from (E)-4-phenyl-buten-2-ol by the vanadium-dependent bromoperoxidase from the alga Corallina officinalis is similar to that of the fungal enzyme but significantly different to the equivalent chemical reaction.

引用

页码：907 / 912

页数：6

共 11 条

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