DOUBLY-STRAPPED PORPHYRINS AS USEFUL BUILDING-BLOCKS FOR SELECTIVELY METALATED OLIGOPORPHYRINS

被引：19

作者：

OSUKA, A ^{[1
]}

NAGATA, T ^{[1
]}

MARUYAMA, K ^{[1
]}

机构：

[1] KYOTO UNIV, FAC SCI, DEPT CHEM, KYOTO 606, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 10期

关键词：

D O I：

10.1246/cl.1991.1687

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metallation of a porphyrin ring was completely suppressed by introducing two (CH2)10 ''straps'' on the both sides of the porphyrin ring. Di- and triporphyrins with one ''doubly-strapped'' ring were quantitatively converted to the partially metallated product with the metal-free strapped ring. These doubly-strapped porphyrins will be useful for synthesis of selectively metallated oligoporphyrins.

引用

页码：1687 / 1690

页数：4

共 24 条

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